Switchable, Reagent‐Controlled Diastereodivergent Photocatalytic Carbocyclisation of Imine‐Derived α‐Amino Radicals

A reagent‐controlled stereodivergent carbocyclisation of aryl aldimine‐derived, photocatalytically generated, α‐amino radicals possessing adjacent conjugated alkenes, affording either bicyclic or tetracyclic products, is described. Under net reductive conditions using commercial Hantzsch ester, the...

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Detalles Bibliográficos
Autores principales: Maitland, J. Andrew P., Leitch, Jamie A., Yamazaki, Ken, Christensen, Kirsten E., Cassar, Doyle J., Hamlin, Trevor A., Dixon, Darren J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597041/
https://www.ncbi.nlm.nih.gov/pubmed/34449968
http://dx.doi.org/10.1002/anie.202107253

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597041/
https://www.ncbi.nlm.nih.gov/pubmed/34449968
http://dx.doi.org/10.1002/anie.202107253

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