Dirhodium Carboxylate Catalysts from 2‐Fenchyloxy or 2‐Menthyloxy Arylacetic Acids: Enantioselective C−H Insertion, Aromatic Addition and Oxonium Ylide Formation/Rearrangement

A new class of dirhodium carboxylate catalysts have been designed and synthesized from 2‐fenchyloxy or 2‐menthyloxy arylacetic acids which display excellent enantioselectivity across a range of transformations of α‐diazocarbonyl compounds. The catalysts were successfully applied to enantioselective...

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Detalles Bibliográficos
Autores principales: Buckley, Aoife M., Crowley, Daniel C., Brouder, Thomas A., Ford, Alan, Rao Khandavilli, U. B., Lawrence, Simon E., Maguire, Anita R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597163/
https://www.ncbi.nlm.nih.gov/pubmed/34820025
http://dx.doi.org/10.1002/cctc.202100924

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597163/
https://www.ncbi.nlm.nih.gov/pubmed/34820025
http://dx.doi.org/10.1002/cctc.202100924

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