Interaction of anions with the surface of a coordination cage in aqueous solution probed by their effect on a cage-catalysed Kemp elimination

An octanuclear M(8)L(12) coordination cage catalyses the Kemp elimination reaction of 5-nitro-1,2-benzisoxazole (NBI) with hydroxide to give 2-cyano-4-nitrophenolate (CNP) as the product. In contrast to the previously-reported very efficient catalysis of the Kemp elimination reaction of unsubstitute...

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Detalles Bibliográficos
Autores principales: Ludden, Michael D., Taylor, Christopher G. P., Tipping, Max B., Train, Jennifer S., Williams, Nicholas H., Dorrat, Jack C., Tuck, Kellie L., Ward, Michael D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597839/
https://www.ncbi.nlm.nih.gov/pubmed/34820094
http://dx.doi.org/10.1039/d1sc04887b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597839/
https://www.ncbi.nlm.nih.gov/pubmed/34820094
http://dx.doi.org/10.1039/d1sc04887b

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