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Organocatalytic cycloaddition–elimination cascade for atroposelective construction of heterobiaryls

The first chiral phosphoric acid (CPA) catalyzed cycloaddition–elimination cascade reaction of 2-naphthol- and phenol-derived enecarbamates with azonaphthalenes has been established, providing a highly atroposelective route to an array of axially chiral aryl-C3-benzoindoles in excellent yields with...

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Detalles Bibliográficos
Autores principales: Xu, Wen-Lei, Zhao, Wei-Ming, Zhang, Ru-Xia, Chen, Jie, Zhou, Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597853/
https://www.ncbi.nlm.nih.gov/pubmed/34820108
http://dx.doi.org/10.1039/d1sc05161j