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Rhodium-catalysed ortho-alkynylation of nitroarenes

The ortho-alkynylation of nitro-(hetero)arenes takes place in the presence of a Rh(iii) catalyst to deliver a wide variety of alkynylated nitroarenes regioselectively. These interesting products could be further derivatized by selective reduction of the nitro group or palladium-catalysed couplings....

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Detalles Bibliográficos
Autores principales: Tan, Eric, Montesinos-Magraner, Marc, García-Morales, Cristina, Mayans, Joan Guillem, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8597868/
https://www.ncbi.nlm.nih.gov/pubmed/34820088
http://dx.doi.org/10.1039/d1sc04527j