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Spontaneous exciton dissociation enables spin state interconversion in delayed fluorescence organic semiconductors

Engineering a low singlet-triplet energy gap (ΔE(ST)) is necessary for efficient reverse intersystem crossing (rISC) in delayed fluorescence (DF) organic semiconductors but results in a small radiative rate that limits performance in LEDs. Here, we study a model DF material, BF2, that exhibits a str...

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Detalles Bibliográficos
Autores principales: Gillett, Alexander J., Tonnelé, Claire, Londi, Giacomo, Ricci, Gaetano, Catherin, Manon, Unson, Darcy M. L., Casanova, David, Castet, Frédéric, Olivier, Yoann, Chen, Weimin M., Zaborova, Elena, Evans, Emrys W., Drummond, Bluebell H., Conaghan, Patrick J., Cui, Lin-Song, Greenham, Neil C., Puttisong, Yuttapoom, Fages, Frédéric, Beljonne, David, Friend, Richard H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8599618/
https://www.ncbi.nlm.nih.gov/pubmed/34789719
http://dx.doi.org/10.1038/s41467-021-26689-8