Transmetalation Reactions Triggered by Electron Transfer between Organocopper Complexes

[Image: see text] [Cu(bipy)(C(6)F(5))] reacts with most aryl iodides to form heterobiphenyls by cross-coupling, but when Rf–I is used (Rf = 3,5-dicholoro-2,4,6-trifluorophenyl), homocoupling products are also formed. Kinetic studies suggest that, for the homocoupling reaction, a mechanism based on t...

Descripción completa

Detalles Bibliográficos
Autores principales: Lozano-Lavilla, Olmo, Gómez-Orellana, Pablo, Lledós, Agustí, Casares, Juan A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8609523/
https://www.ncbi.nlm.nih.gov/pubmed/34259512
http://dx.doi.org/10.1021/acs.inorgchem.1c01595

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8609523/
https://www.ncbi.nlm.nih.gov/pubmed/34259512
http://dx.doi.org/10.1021/acs.inorgchem.1c01595

Ejemplares similares