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Transmetalation Reactions Triggered by Electron Transfer between Organocopper Complexes
[Image: see text] [Cu(bipy)(C(6)F(5))] reacts with most aryl iodides to form heterobiphenyls by cross-coupling, but when Rf–I is used (Rf = 3,5-dicholoro-2,4,6-trifluorophenyl), homocoupling products are also formed. Kinetic studies suggest that, for the homocoupling reaction, a mechanism based on t...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8609523/ https://www.ncbi.nlm.nih.gov/pubmed/34259512 http://dx.doi.org/10.1021/acs.inorgchem.1c01595 |