Stereoselective Alkylation of Chiral Titanium(IV) Enolates with tert-Butyl Peresters

[Image: see text] Here, we present a new stereoselective alkylation of titanium(IV) enolates of chiral N-acyl oxazolidinones with tert-butyl peresters from Cα-branched aliphatic carboxylic acids, which proceeds through the decarboxylation of the peresters and the subsequent formation of alkyl radica...

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Detalles Bibliográficos
Autores principales: Pérez-Palau, Marina, Sanosa, Nil, Romea, Pedro, Urpí, Fèlix, López, Rosa, Gómez-Bengoa, Enrique, Font-Bardia, Mercè
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8609576/
https://www.ncbi.nlm.nih.gov/pubmed/34699246
http://dx.doi.org/10.1021/acs.orglett.1c03366

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8609576/
https://www.ncbi.nlm.nih.gov/pubmed/34699246
http://dx.doi.org/10.1021/acs.orglett.1c03366

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