Dynamics and Entropy of Cyclohexane Rings Control pH-Responsive Reactivity

[Image: see text] Activation entropy (ΔS(‡)) is not normally considered the main factor in determining the reactivity of unimolecular reactions. Here, we report that the intramolecular degradation of six-membered ring compounds is mainly determined by the ΔS(‡), which is strongly influenced by the r...

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Detalles Bibliográficos
Autores principales: Kang, Sunyoung, Noh, Chanwoo, Kang, Hyosik, Shin, Ji-Yeon, Kim, So-Young, Kim, Seulah, Son, Moon-Gi, Park, Eunseok, Song, Hyun Kyu, Shin, Seokmin, Lee, Sanghun, Kim, Nak-Kyoon, Jung, YounJoon, Lee, Yan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8611792/
https://www.ncbi.nlm.nih.gov/pubmed/34841418
http://dx.doi.org/10.1021/jacsau.1c00354

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8611792/
https://www.ncbi.nlm.nih.gov/pubmed/34841418
http://dx.doi.org/10.1021/jacsau.1c00354

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