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Dynamics and Entropy of Cyclohexane Rings Control pH-Responsive Reactivity
[Image: see text] Activation entropy (ΔS(‡)) is not normally considered the main factor in determining the reactivity of unimolecular reactions. Here, we report that the intramolecular degradation of six-membered ring compounds is mainly determined by the ΔS(‡), which is strongly influenced by the r...
| Autores principales: | , , , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8611792/ https://www.ncbi.nlm.nih.gov/pubmed/34841418 http://dx.doi.org/10.1021/jacsau.1c00354 |