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Halogenation of a twisted non-polar π-system as a tool to modulate phosphorescence at room temperature

Halogenation of a twisted three-fold symmetric hydrocarbon with F, Cl or Br leads to strong modulation of triplet–triplet annihilation and dual phosphorescence, one thermally activated and the other very persistent and visible by eye, with different relative contributions depending on the halide. Th...

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Detalles Bibliográficos
Autores principales: Farias, Giliandro, Salla, Cristian A. M., Aydemir, Murat, Sturm, Ludmilla, Dechambenoit, Pierre, Durola, Fabien, de Souza, Bernardo, Bock, Harald, Monkman, Andrew P., Bechtold, Ivan H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8612374/
https://www.ncbi.nlm.nih.gov/pubmed/34909153
http://dx.doi.org/10.1039/d1sc04936d