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Synthesis of Polypeptides with High-Fidelity Terminal Functionalities under NCA Monomer-Starved Conditions
Controlled polypeptide synthesis via α-amino acid N-carboxylic anhydride (NCA) polymerization using conventional primary amine initiators encounters two major obstacles: (i) normal amine mechanism (NAM) and activated monomer mechanism (AMM) coexist due to amine basicity and nucleophilicity and (ii)...
Autores principales: | Li, Lei, Cen, Jie, Pan, Wenhao, Zhang, Yuben, Leng, Xuanxi, Tan, Zhengqi, Yin, Hao, Liu, Shiyong |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
AAAS
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8617576/ https://www.ncbi.nlm.nih.gov/pubmed/34877538 http://dx.doi.org/10.34133/2021/9826046 |
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