Radical and Ionic Mechanisms in Rearrangements of o-Tolyl Aryl Ethers and Amines Initiated by the Grubbs–Stoltz Reagent, Et(3)SiH/KO(t)Bu

Rearrangements of o-tolyl aryl ethers, amines, and sulfides with the Grubbs–Stoltz reagent (Et(3)SiH + KO(t)Bu) were recently announced, in which the ethers were converted to o-hydroxydiarylmethanes, while the (o-tol)(Ar)NH amines were transformed into dihydroacridines. Radical mechanisms were propo...

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Detalles Bibliográficos
Autores principales: Kolodziejczak, Krystian, Stewart, Alexander J., Tuttle, Tell, Murphy, John A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8619283/
https://www.ncbi.nlm.nih.gov/pubmed/34833971
http://dx.doi.org/10.3390/molecules26226879

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8619283/
https://www.ncbi.nlm.nih.gov/pubmed/34833971
http://dx.doi.org/10.3390/molecules26226879

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