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Structural Requirements of 1-(2-Pyridinyl)-5-pyrazolones for Disproportionation of Boronic Acids

We observed an unusual formation of four-coordinate boron(III) complexes from the reaction of 1-(2-pyridinyl)-5-pyrazolone derivatives with arylboronic acids in the basic media. The exact mechanism is not clear; however, the use of unprotected boronic acid and the presence of a bidentate ligand appe...

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Detalles Bibliográficos
Autores principales: Cho, Joungmo, Sadu, Venkata Subbaiah, Han, Yohan, Bae, Yunsoo, Lee, Hwajeong, Lee, Kee-In
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8623043/
https://www.ncbi.nlm.nih.gov/pubmed/34833904
http://dx.doi.org/10.3390/molecules26226814