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Tracing the Incorporation of the “9(th) Sulfur” into the Nitrogenase Cofactor Precursor with Selenite and Tellurite
The Mo-nitrogenase catalyzes the reduction of N(2) to NH(3) at its cofactor, an [(R-homocitrate)MoFe(7)S(9)C] cluster synthesized via the formation of a [Fe(8)S(9)C] L-cluster prior to the insertion of Mo and homocitrate. Previously, we have identified a [Fe(8)S(8)C] L*-cluster, which is homologous...
Autores principales: | , , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8629924/ https://www.ncbi.nlm.nih.gov/pubmed/34635813 http://dx.doi.org/10.1038/s41557-021-00799-8 |