Tracing the Incorporation of the “9(th) Sulfur” into the Nitrogenase Cofactor Precursor with Selenite and Tellurite

The Mo-nitrogenase catalyzes the reduction of N(2) to NH(3) at its cofactor, an [(R-homocitrate)MoFe(7)S(9)C] cluster synthesized via the formation of a [Fe(8)S(9)C] L-cluster prior to the insertion of Mo and homocitrate. Previously, we have identified a [Fe(8)S(8)C] L*-cluster, which is homologous...

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Detalles Bibliográficos
Autores principales: Tanifuji, Kazuki, Jasniewski, Andrew J., Villarreal, David, Stiebritz, Martin T., Lee, Chi Chung, Wilcoxen, Jarett, Okhi, Yasuhiro, Chatterjee, Ruchira, Bogacz, Isabel, Yano, Junko, Kern, Jan, Hedman, Britt, Hodgson, Keith O., Britt, R. David, Hu, Yilin, Ribbe, Markus W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8629924/
https://www.ncbi.nlm.nih.gov/pubmed/34635813
http://dx.doi.org/10.1038/s41557-021-00799-8

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