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Synthesis and photophysical properties of linear gold(i) complexes based on a CCC carbene

The reaction between allenylpyridine (L1) and (Me(2)S)AuCl resulted in the quantitative formation of the (Indolizy)gold chloride complex 1 (Indolizy = indolizin-2-ylidene). The reaction of 1 with carbazole in the presence of KO(t)Bu affords the corresponding (Indolizy)Au(Cz) complex 2. Both compound...

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Detalles Bibliográficos
Autores principales: Romanov, Alexander S., Linnolahti, Mikko, Bochmann, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8631002/
https://www.ncbi.nlm.nih.gov/pubmed/34781337
http://dx.doi.org/10.1039/d1dt03393j