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Silole allylic anions instead of silanides

Reaction of a 3,4-diphenylsilole with two neopentasilanyl groups attached to the 2- and 5-positions with one equivalent of KO(t)Bu did not result in the expected silanide formation but yielded a silole allylic anion instead. The initially formed silanide added to a neighboring phenyl group, which th...

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Detalles Bibliográficos
Autores principales: Pöcheim, Alexander, Albers, Lena, Müller, Thomas, Baumgartner, Judith, Marschner, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8631112/
https://www.ncbi.nlm.nih.gov/pubmed/34779457
http://dx.doi.org/10.1039/d1dt02363b