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Direct metal–carbon bonding in symmetric bis(C–H) agostic nickel(i) complexes

Agostic interactions are examples of σ-type interactions, typically resulting from interactions between C–H σ-bonds with empty transition metal d orbitals. Such interactions often reflect the first step in transition metal-catalysed C–H activation processes and thus are of critical importance in und...

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Detalles Bibliográficos
Autores principales: He, Weiying, Beattie, D. Dawson, Zhou, Hao, Bowes, Eric G., Schafer, Laurel L., Love, Jennifer A., Kennepohl, Pierre
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8635179/
https://www.ncbi.nlm.nih.gov/pubmed/34976350
http://dx.doi.org/10.1039/d1sc03578a