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Intermolecular CDC amination of remote and proximal unactivated C(sp(3))–H bonds through intrinsic substrate reactivity – expanding towards a traceless directing group
An intermolecular radical based distal selectivity in appended alkyl chains has been developed. The selectivity is maximum when the distal carbon is γ to the appended group and decreases by moving from γ → δ → ε positions. In –COO– linked alkyl chains, the same distal γ-selectivity is observed irres...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8635183/ https://www.ncbi.nlm.nih.gov/pubmed/34976352 http://dx.doi.org/10.1039/d1sc04365j |