Asymmetric synthesis of dibenzo[b,d]azepines by Cu-catalyzed reductive or borylative cyclization

A copper-catalyzed asymmetric intramolecular reductive cyclization for the synthesis of dibenzo[b,d]azepines is described. Use of 2′-vinyl-biaryl-2-imines as substrates and in situ formed [Cu(I)/(Ph-BPE)] as the catalyst enables the synthesis of 7-membered bridged biarylamines containing both centra...

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Detalles Bibliográficos
Autores principales: Rodríguez-Salamanca, Patricia, Martín-de la Calle, Rocío, Rodríguez, Verónica, Merino, Pedro, Fernández, Rosario, Lassaletta, José M., Hornillos, Valentín
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8635211/
https://www.ncbi.nlm.nih.gov/pubmed/34976349
http://dx.doi.org/10.1039/d1sc04980a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8635211/
https://www.ncbi.nlm.nih.gov/pubmed/34976349
http://dx.doi.org/10.1039/d1sc04980a

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