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Hydroxylamine-mediated C–C amination via an aza-hock rearrangement

Despite the widespread use of anilines, synthetic challenges to these targets still exist. Selectivity is often an issue, when using the traditional nitration-reduction sequence or more modern approaches, including arene C–H aminations catalyzed by transition metals, photosensitizers, or electrodes....

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Detalles Bibliográficos
Autores principales: Wang, Tao, Stein, Philipp M., Shi, Hongwei, Hu, Chao, Rudolph, Matthias, Hashmi, A. Stephen K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8640056/
https://www.ncbi.nlm.nih.gov/pubmed/34857758
http://dx.doi.org/10.1038/s41467-021-27271-y