Effect of tert-butyl groups on electronic communication between redox units in tetrathiafulvalene-tetraazapyrene triads

The electronic effect of tert-butyl groups on intramolecular through-bond interactions between redox units in tetrathiafulvalene-tetraazapyrene (TAP) triads is investigated. The insertion of tert-butyl groups raises the TAP-localised LUMO level by 0.21 eV, in fairly good agreement with 0.17 eV deter...

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Detalles Bibliográficos
Autores principales: Zhou, Ping, Aschauer, Ulrich, Decurtins, Silvio, Feurer, Thomas, Häner, Robert, Liu, Shi-Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8640732/
https://www.ncbi.nlm.nih.gov/pubmed/34792067
http://dx.doi.org/10.1039/d1cc05671a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8640732/
https://www.ncbi.nlm.nih.gov/pubmed/34792067
http://dx.doi.org/10.1039/d1cc05671a

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