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Effect of tert-butyl groups on electronic communication between redox units in tetrathiafulvalene-tetraazapyrene triads
The electronic effect of tert-butyl groups on intramolecular through-bond interactions between redox units in tetrathiafulvalene-tetraazapyrene (TAP) triads is investigated. The insertion of tert-butyl groups raises the TAP-localised LUMO level by 0.21 eV, in fairly good agreement with 0.17 eV deter...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8640732/ https://www.ncbi.nlm.nih.gov/pubmed/34792067 http://dx.doi.org/10.1039/d1cc05671a |