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A crystalline radical cation derived from Thiele’s hydrocarbon with redox range beyond 1 V

Thiele’s hydrocarbon occupies a central role as an open-shell platform for new organic materials, however little is known about its redox behaviour. While recent synthetic approaches involving symmetrical carbene substitution of the CPh(2) termini yield isolable neutral/dicationic analogues, the int...

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Detalles Bibliográficos
Autores principales: Loh, Ying Kai, Vasko, Petra, McManus, Caitilín, Heilmann, Andreas, Myers, William K., Aldridge, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8642399/
https://www.ncbi.nlm.nih.gov/pubmed/34862371
http://dx.doi.org/10.1038/s41467-021-27104-y