Tautomerism troubles: proton transfer modifies the stereochemical assignments in diastereoisomeric structures of spiro­cyclic 5-methyl-2H-imidazol-4-amine dimers

During the racemization of a novel pharmaceutical spiro­cyclic imidazole–amine compound, namely, 6′-bromo-N-(6′-bromo-4-meth­oxy-4′′-methyl-3′H-di­spiro[cyclo­hexane-1,2′-indene-1′,2′′-imidazol]-5′′-yl)-4-meth­oxy-4′′-methyl-3′H-di­spiro­[cyclo­hexane-1,2′-indene-1′,2′′-imidazol]-5′′-imine, C(36)H(4...

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Detalles Bibliográficos
Autores principales: Blade, Helen, Horton, Peter N., Morrison, James A., Orton, James B., Sullivan, Rachel A., Coles, Simon J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647748/
https://www.ncbi.nlm.nih.gov/pubmed/34925905
http://dx.doi.org/10.1107/S205698902100668X

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8647748/
https://www.ncbi.nlm.nih.gov/pubmed/34925905
http://dx.doi.org/10.1107/S205698902100668X

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