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Basicity as a Thermodynamic Descriptor of Carbanions Reactivity with Carbon Dioxide: Application to the Carboxylation of α,β-Unsaturated Ketones

The utilization of carbon dioxide as a raw material represents nowadays an appealing strategy in the renewable energy, organic synthesis, and green chemistry fields. Besides reduction strategies, carbon dioxide can be exploited as a single-carbon-atom building block through its fixation into organic...

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Detalles Bibliográficos
Autores principales: Franceschi, Pietro, Nicoletti, Catia, Bonetto, Ruggero, Bonchio, Marcella, Natali, Mirco, Dell’Amico, Luca, Sartorel, Andrea
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8652261/
https://www.ncbi.nlm.nih.gov/pubmed/34900942
http://dx.doi.org/10.3389/fchem.2021.783993