Closo- or Nido-Carborane Diphosphane as Responsible for Strong Thermochromism or Time Activated Delayed Fluorescence (TADF) in [Cu(N^N)(P^P)](0/+)

[Image: see text] Ortho-closo or ortho-nido-carborane-diphosphanes have been selected to prepare the heteroleptic cationic or neutral [Cu(N^N){(PPh(2))(2)C(2)B(10)H(10)}]PF(6) (1) and [Cu(N^N){(PPh(2))(2)C(2)B(9)H(10)}] (2) [N^N = 2-(4-thiazolyl)benzimidazole], respectively. Complexes 1 and 2 displa...

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Detalles Bibliográficos
Autores principales: Alconchel, Adrián, Crespo, Olga, García-Orduña, Pilar, Gimeno, M. Concepción
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8653344/
https://www.ncbi.nlm.nih.gov/pubmed/34812617
http://dx.doi.org/10.1021/acs.inorgchem.1c03092

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8653344/
https://www.ncbi.nlm.nih.gov/pubmed/34812617
http://dx.doi.org/10.1021/acs.inorgchem.1c03092

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