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Closo- or Nido-Carborane Diphosphane as Responsible for Strong Thermochromism or Time Activated Delayed Fluorescence (TADF) in [Cu(N^N)(P^P)](0/+)
[Image: see text] Ortho-closo or ortho-nido-carborane-diphosphanes have been selected to prepare the heteroleptic cationic or neutral [Cu(N^N){(PPh(2))(2)C(2)B(10)H(10)}]PF(6) (1) and [Cu(N^N){(PPh(2))(2)C(2)B(9)H(10)}] (2) [N^N = 2-(4-thiazolyl)benzimidazole], respectively. Complexes 1 and 2 displa...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8653344/ https://www.ncbi.nlm.nih.gov/pubmed/34812617 http://dx.doi.org/10.1021/acs.inorgchem.1c03092 |