Second-sphere effects on H(2)O(2) activation by non-heme Fe(II) complexes: role of a phenol group in the [H(2)O(2)]-dependent accumulation of Fe(IV)O vs. Fe(III)OOH

Redox metalloenzymes achieve very selective oxidation reactions under mild conditions using O(2) or H(2)O(2) as oxidants and release harmless side-products like water. Their oxidation selectivity is intrinsically linked to the control of the oxidizing species generated during the catalytic cycle. To...

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Detalles Bibliográficos
Autores principales: Rebilly, Jean-Noël, Herrero, Christian, Sénéchal-David, Katell, Guillot, Régis, Inceoglu, Tanya, Maisonneuve, Hélène, Banse, Frédéric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8653992/
https://www.ncbi.nlm.nih.gov/pubmed/35003600
http://dx.doi.org/10.1039/d1sc03303d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8653992/
https://www.ncbi.nlm.nih.gov/pubmed/35003600
http://dx.doi.org/10.1039/d1sc03303d

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