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Proton to hydride umpolung at a phosphonium center via electron relay: a new strategy for main-group based water reduction

Generation of dihydrogen from water splitting, also known as water reduction, is a key process to access a sustainable hydrogen economy for energy production and usage. The key step is the selective reduction of a protic hydrogen to an accessible and reactive hydride, which has proven difficult at a...

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Detalles Bibliográficos
Autores principales: Oishi, Takumi, Lugo-Fuentes, Leonardo I., Jing, Yichuan, Jimenez-Halla, J. Oscar C., Barroso-Flores, Joaquín, Nakamoto, Masaaki, Yamamoto, Yohsuke, Tsunoji, Nao, Shang, Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8654027/
https://www.ncbi.nlm.nih.gov/pubmed/35003590
http://dx.doi.org/10.1039/d1sc05135k