A photoexcited halogen-bonded EDA complex of the thiophenolate anion with iodobenzene for C(sp(3))–H activation and thiolation

Thiophenol was discovered to form an EDA complex with iodobenzene through halogen bonding interactions upon treatment with KOH. A direct photochemical thiolation of C(sp(3))–H bond-containing etheric, allylic, and benzylic substrates with thiophenol was developed. The reaction proceeded on the basis...

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Detalles Bibliográficos
Autores principales: Li, Tao, Liang, Kangjiang, Tang, Jiaying, Ding, Yuzhen, Tong, Xiaogang, Xia, Chengfeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8654056/
https://www.ncbi.nlm.nih.gov/pubmed/35003596
http://dx.doi.org/10.1039/d1sc03667j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8654056/
https://www.ncbi.nlm.nih.gov/pubmed/35003596
http://dx.doi.org/10.1039/d1sc03667j

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