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Ir-catalyzed enantioselective B−H alkenylation for asymmetric synthesis of chiral-at-cage o‑carboranes

The asymmetric synthesis of chiral-at-cage o-carboranes, whose chirality is associated with the substitution patterns on the polyhedron, is of great interest as the icosahedral carboranes have wide applications in medicinal and materials chemistry. Herein we report an intermolecular Ir-catalyzed ena...

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Detalles Bibliográficos
Autores principales: Cheng, Ruofei, Zhang, Jie, Zhang, Huifang, Qiu, Zaozao, Xie, Zuowei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8654863/
https://www.ncbi.nlm.nih.gov/pubmed/34880231
http://dx.doi.org/10.1038/s41467-021-27441-y