Mimicking Elementary Reactions of Manganese Lipoxygenase Using Mn-hydroxo and Mn-alkylperoxo Complexes

Manganese lipoxygenase (MnLOX) is an enzyme that converts polyunsaturated fatty acids to alkyl hydroperoxides. In proposed mechanisms for this enzyme, the transfer of a hydrogen atom from a substrate C-H bond to an active-site Mn(III)-hydroxo center initiates substrate oxidation. In some proposed me...

Descripción completa

Detalles Bibliográficos
Autores principales: Opalade, Adedamola A., Grotemeyer, Elizabeth N., Jackson, Timothy A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659247/
https://www.ncbi.nlm.nih.gov/pubmed/34885729
http://dx.doi.org/10.3390/molecules26237151

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659247/
https://www.ncbi.nlm.nih.gov/pubmed/34885729
http://dx.doi.org/10.3390/molecules26237151

Ejemplares similares