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Mimicking Elementary Reactions of Manganese Lipoxygenase Using Mn-hydroxo and Mn-alkylperoxo Complexes

Manganese lipoxygenase (MnLOX) is an enzyme that converts polyunsaturated fatty acids to alkyl hydroperoxides. In proposed mechanisms for this enzyme, the transfer of a hydrogen atom from a substrate C-H bond to an active-site Mn(III)-hydroxo center initiates substrate oxidation. In some proposed me...

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Detalles Bibliográficos
Autores principales:	Opalade, Adedamola A., Grotemeyer, Elizabeth N., Jackson, Timothy A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8659247/ https://www.ncbi.nlm.nih.gov/pubmed/34885729 http://dx.doi.org/10.3390/molecules26237151

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