Manganese(I)-Catalyzed H–P Bond Activation via Metal–Ligand Cooperation

[Image: see text] Here we report that chiral Mn(I) complexes are capable of H–P bond activation. This activation mode enables a general method for the hydrophosphination of internal and terminal α,β-unsaturated nitriles. Metal−ligand cooperation, a strategy previously not considered for catalytic H–...

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Detalles Bibliográficos
Autores principales: Pérez, Juana M., Postolache, Roxana, Castiñeira Reis, Marta, Sinnema, Esther G., Vargová, Denisa, de Vries, Folkert, Otten, Edwin, Ge, Luo, Harutyunyan, Syuzanna R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8662621/
https://www.ncbi.nlm.nih.gov/pubmed/34797634
http://dx.doi.org/10.1021/jacs.1c10756

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8662621/
https://www.ncbi.nlm.nih.gov/pubmed/34797634
http://dx.doi.org/10.1021/jacs.1c10756

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