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1-Zirconacyclobuta-2,3-dienes: synthesis of organometallic analogs of elusive 1,2-cyclobutadiene, unprecedented intramolecular C–H activation, and reactivity studies

The structure, bonding, and reactivity of small, highly unsaturated ring systems is of fundamental interest for inorganic and organic chemistry. Four-membered metallacyclobuta-2,3-dienes, also referred to as metallacycloallenes, are among the most exotic examples for ring systems as these represent...

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Detalles Bibliográficos
Autores principales: Shi, Xinzhe, Li, Sihan, Reiß, Melanie, Spannenberg, Anke, Holtrichter-Rößmann, Thorsten, Reiß, Fabian, Beweries, Torsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8672727/
https://www.ncbi.nlm.nih.gov/pubmed/35024129
http://dx.doi.org/10.1039/d1sc06052j