Cargando…

1-Zirconacyclobuta-2,3-dienes: synthesis of organometallic analogs of elusive 1,2-cyclobutadiene, unprecedented intramolecular C–H activation, and reactivity studies

The structure, bonding, and reactivity of small, highly unsaturated ring systems is of fundamental interest for inorganic and organic chemistry. Four-membered metallacyclobuta-2,3-dienes, also referred to as metallacycloallenes, are among the most exotic examples for ring systems as these represent...

Descripción completa

Detalles Bibliográficos
Autores principales:	Shi, Xinzhe, Li, Sihan, Reiß, Melanie, Spannenberg, Anke, Holtrichter-Rößmann, Thorsten, Reiß, Fabian, Beweries, Torsten
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8672727/ https://www.ncbi.nlm.nih.gov/pubmed/35024129 http://dx.doi.org/10.1039/d1sc06052j

Ejemplares similares

1-Titanacyclobuta-2,3-diene – an elusive four-membered cyclic allene
por: Reiß, Fabian, et al.
Publicado: (2019)

Crystal structure of 1,1,2,2-tetramethyl-1,2-bis(2,3,4,5-tetramethylcyclopenta-2,4-dien-1-yl)disilane
por: Godemann, Christian, et al.
Publicado: (2015)

Dimerisation of Dipiperidinoacetylene: Convenient Access to Tetraamino‐1,3‐Cyclobutadiene and Tetraamino‐1,2‐Cyclobutadiene Metal Complexes
por: Hackl, Ludwig, et al.
Publicado: (2019)

Mono- and dinuclear zirconocene(iv) amide complexes for the catalytic dehydropolymerisation of phenylsilane
por: Lindenau, Kevin, et al.
Publicado: (2022)

{N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-κ(2) P,P′}bis(η(5)-cyclopentadienyl)titanium(II)
por: Haehnel, Martin, et al.
Publicado: (2013)

Switching on Elusive Organometallic Mechanisms with Photoredox Catalysis
por: Terrett, Jack A., et al.
Publicado: (2015)

Haptotropism in a Nickel Complex with a Neutral, π‐Bridging cyclo‐P(4) Ligand Analogous to Cyclobutadiene
por: Gendy, Chris, et al.
Publicado: (2022)

Crystal structure of 1-hydroxy-2,2,6,6-tetramethylpiperidin-1-ium trifluoromethanesulfonate
por: Godemann, Christian, et al.
Publicado: (2015)

Synthesis and crystallographic characterization of [2,2-bis(η(5)-pentamethylcyclopentadienyl)-3,4-bis(trimethylsilyl)-2-zirconafuran-5-one-κO (5)]triisobutylaluminium
por: Burlakov, Vladimir V., et al.
Publicado: (2018)

Diastereoselectivity on Intramolecular Alder‐ene Reaction of 1,6‐Dienes
por: de Cózar, Abel
Publicado: (2022)

Crystal structure of tricarbonyl(N-diphenylphosphanyl-N,N′-diisopropyl-P-phenylphosphonous diamide-κ(2) P,P′)cobalt(I) tetracarbonylcobaltate(−I) toluene 0.25-solvate
por: Dura, Laura, et al.
Publicado: (2014)

Intermolecular hydrogen bonding in isostructural pincer complexes [OH-((t-Bu)POCOP(t-Bu))MCl] (M = Pd and Pt)
por: Joksch, Markus, et al.
Publicado: (2019)

[1-Dimethylsilyl-2-phenyl-3-(η(5)-tetramethylcyclopentadienyl)prop-1-en-1-yl-κC (1)](η(5)-pentamethylcyclopentadienyl)titanium(III)
por: Lamač, Martin, et al.
Publicado: (2009)

Iodidobis(η(5)-pentamethylcyclopentadienyl)titanium(III)
por: Kessler, Monty, et al.
Publicado: (2010)

Cycloadditions with a Stable Charge‐Separated Cyclobutadiene‐Type Amido‐Substituted Silicon Ring Compound
por: Keuter, Jan, et al.
Publicado: (2021)

Ru-catalysed oxidative cyclisation of 1,5-dienes: an unprecedented role for the co-oxidant
por: Hussein, Aqeel A.
Publicado: (2020)

Tris(η(5)-cyclopentadienyl)hafnium(III)
por: Burlakov, Vladimir V., et al.
Publicado: (2011)

(η(5)-Cyclopentadienyl)bis(triphenylphosphane)cobalt(I)–toluene–n-hexane (1/0.20/0.25)
por: Hapke, Marko, et al.
Publicado: (2008)

Crystal structures of two ansa-titanocene trifluoromethanesulfonate complexes bearing the Me(2)Si(C(5)Me(4))(2) ligand
por: Kessler, Monty, et al.
Publicado: (2016)

(tert-Butylimido)bis(η(5)-cyclopentadienyl)pyridinezirconium(IV)
por: Kaleta, Katharina, et al.
Publicado: (2010)

Dehydropolymerisation of Methylamine Borane and an N‐Substituted Primary Amine Borane Using a PNP Fe Catalyst
por: Anke, Felix, et al.
Publicado: (2020)

The Application of Reversible Intramolecular Sulfonamide Ligation to Modulate Reactivity in Organometallic Ruthenium(II) Diamine Complexes
por: Kemp, Samuel A., et al.
Publicado: (2020)

(μ(3)-Hydrido)[μ(3)-2-(trimethylsilyl)ethylidyne-κ(3) C (1):C (1):C (1)]tetrakis[(η(5)-cyclopentadienyl)cobalt(II)]
por: Haehnel, Martin, et al.
Publicado: (2013)

A Comparative Study on the Thermodynamics of Halogen Bonding of Group 10 Pincer Fluoride Complexes
por: Joksch, Markus, et al.
Publicado: (2020)

Bis(μ(2)-isopropylimido-κ(2) N:N)bis[(η(5)-cyclopentadienyl)(ethenolato-κO)titanium(IV)]
por: Haehnel, Martin, et al.
Publicado: (2013)

Crystal structure of bis(η(5)-cyclopentadienyl)(2,3-diethylbutane-1,4-diyl)hafnium(IV)
por: Burlakov, Vladimir V., et al.
Publicado: (2015)

{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC (1)}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate
por: Selent, Detlef, et al.
Publicado: (2012)

Crystal structure of di-n-butylbis(η (5)-pentamethylcyclopentadienyl)hafnium(IV)
por: Arndt, Perdita, et al.
Publicado: (2015)

(Cyanido-κC)(2,2-diphenylacetamido-κ(2) N,O)bis(η(5)-pentamethylcyclopentadienyl)zirconium(IV)
por: Becker, Lisanne, et al.
Publicado: (2014)

Crystal structure of bis(η(5)-cyclopentadienyl)(1,4-di-tert-butylbuta-1-en-3-yn-1-yl)zirconium(IV) μ(2)-hydroxido-bis[tris(pentafluorophenyl)borate]
por: Burlakov, Vladimir V., et al.
Publicado: (2015)

Organometallics
por: Bochmann, Manfred
Publicado: (1994)

Formation of trisubstituted buta-1,3-dienes and α,β-unsaturated ketones via the reaction of functionalized vinyl phosphates and vinyl phosphordiamidates with organometallic reagents
por: Oeser, Petr, et al.
Publicado: (2020)

2-Bromo-6-(chlorodiisopropylsilyl)phenyl tosylate as an efficient platform for intramolecular benzyne–diene [4 + 2] cycloaddition
por: Nishii, Arata, et al.
Publicado: (2019)

Crystal structure of bis{μ(2)-[(2-iminocyclopentylidene)methylidene]azanido-κ(2) N:N′}bis[(η(5)-pentamethylcyclopentadienyl)zirconium(IV)] hexane monosolvate
por: Becker, Lisanne, et al.
Publicado: (2015)

Organometallic Chemistry
por: Spessard, Gary O
Publicado: (1997)

Organometallic chemistry
por: Straub, Bernd F, et al.
Publicado: (2016)

Comprehensive organometallic chemistry : the synthesis, reactions, and structures of organometallic compounds /
Publicado: (1982)

Surprising Homolytic Gas Phase Co−C Bond Dissociation Energies of Organometallic Aryl‐Cobinamides Reveal Notable Non‐Bonded Intramolecular Interactions
por: Tsybizova, Alexandra, et al.
Publicado: (2021)

Unprecedented
Publicado: (1898)

Principles of organometallic chemistry
por: Powell, P
Publicado: (1988)

Cannot write session to /tmp/vufind_sessions/sess_jjvhpufe73p9s550u204koookd