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Abiotic reduction of ketones with silanes catalyzed by carbonic anhydrase through an enzymatic zinc hydride
Enzymatic reactions through mononuclear metal hydrides are unknown in nature, despite the prevalence of such intermediates in the reactions of synthetic transition-metal catalysts. If metalloenzymes would react through abiotic intermediates like these, then the scope of enzyme-catalyzed reactions wo...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8675236/ https://www.ncbi.nlm.nih.gov/pubmed/33603222 http://dx.doi.org/10.1038/s41557-020-00633-7 |