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Increasing the steric hindrance around the catalytic core of a self-assembled imine-based non-heme iron catalyst for C–H oxidation

Sterically hindered imine-based non-heme complexes 4 and 5 rapidly self-assemble in acetonitrile at 25 °C, when the corresponding building blocks are added in solution in the proper ratios. Such complexes are investigated as catalysts for the H(2)O(2) oxidation of a series of substrates in order to...

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Detalles Bibliográficos
Autores principales: Frateloreto, Federico, Capocasa, Giorgio, Olivo, Giorgio, Abdel Hady, Karim, Sappino, Carla, Di Berto Mancini, Marika, Levi Mortera, Stefano, Lanzalunga, Osvaldo, Di Stefano, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8690968/
https://www.ncbi.nlm.nih.gov/pubmed/35423066
http://dx.doi.org/10.1039/d0ra09677f