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Hydroboration of nitriles and imines by highly active zinc dihydride catalysts

Eco-friendly zinc dihydrides stabilized by N-heterocyclic carbenes were demonstrated to be highly efficient catalysts for the double hydroboration of nitriles with pinacolborane, exhibiting turnover frequencies up to 3000 h(−1) at room temperature under solvent-free conditions. The reactions afforde...

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Detalles Bibliográficos
Autores principales: Wang, Xiaoming, Xu, Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8693426/
https://www.ncbi.nlm.nih.gov/pubmed/35423703
http://dx.doi.org/10.1039/d0ra09648b