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Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt

The scope of the Giese reaction is expanded using readily available alkyl tosylates as substrates and nucleophilic cobalt(i) catalysts under visible-light irradiation. The reaction proceeds preferentially with less bulky primary alkyl tosylates. This unique reactivity enables the regio-selective Gie...

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Detalles Bibliográficos
Autores principales: Komeyama, Kimihiro, Michiyuki, Takuya, Teshima, Yoshikazu, Osaka, Itaru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8693991/
https://www.ncbi.nlm.nih.gov/pubmed/35424301
http://dx.doi.org/10.1039/d0ra10739e