Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt

The scope of the Giese reaction is expanded using readily available alkyl tosylates as substrates and nucleophilic cobalt(i) catalysts under visible-light irradiation. The reaction proceeds preferentially with less bulky primary alkyl tosylates. This unique reactivity enables the regio-selective Gie...

Descripción completa

Detalles Bibliográficos
Autores principales: Komeyama, Kimihiro, Michiyuki, Takuya, Teshima, Yoshikazu, Osaka, Itaru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8693991/
https://www.ncbi.nlm.nih.gov/pubmed/35424301
http://dx.doi.org/10.1039/d0ra10739e
_version_ 1784619257106006016
author Komeyama, Kimihiro
Michiyuki, Takuya
Teshima, Yoshikazu
Osaka, Itaru
author_facet Komeyama, Kimihiro
Michiyuki, Takuya
Teshima, Yoshikazu
Osaka, Itaru
author_sort Komeyama, Kimihiro
collection PubMed
description The scope of the Giese reaction is expanded using readily available alkyl tosylates as substrates and nucleophilic cobalt(i) catalysts under visible-light irradiation. The reaction proceeds preferentially with less bulky primary alkyl tosylates. This unique reactivity enables the regio-selective Giese reaction of polyol derivatives.
format Online
Article
Text
id pubmed-8693991
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-86939912022-04-13 Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt Komeyama, Kimihiro Michiyuki, Takuya Teshima, Yoshikazu Osaka, Itaru RSC Adv Chemistry The scope of the Giese reaction is expanded using readily available alkyl tosylates as substrates and nucleophilic cobalt(i) catalysts under visible-light irradiation. The reaction proceeds preferentially with less bulky primary alkyl tosylates. This unique reactivity enables the regio-selective Giese reaction of polyol derivatives. The Royal Society of Chemistry 2021-01-18 /pmc/articles/PMC8693991/ /pubmed/35424301 http://dx.doi.org/10.1039/d0ra10739e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Komeyama, Kimihiro
Michiyuki, Takuya
Teshima, Yoshikazu
Osaka, Itaru
Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt
title Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt
title_full Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt
title_fullStr Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt
title_full_unstemmed Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt
title_short Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt
title_sort visible light-driven giese reaction with alkyl tosylates catalysed by nucleophilic cobalt
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8693991/
https://www.ncbi.nlm.nih.gov/pubmed/35424301
http://dx.doi.org/10.1039/d0ra10739e
work_keys_str_mv AT komeyamakimihiro visiblelightdrivengiesereactionwithalkyltosylatescatalysedbynucleophiliccobalt
AT michiyukitakuya visiblelightdrivengiesereactionwithalkyltosylatescatalysedbynucleophiliccobalt
AT teshimayoshikazu visiblelightdrivengiesereactionwithalkyltosylatescatalysedbynucleophiliccobalt
AT osakaitaru visiblelightdrivengiesereactionwithalkyltosylatescatalysedbynucleophiliccobalt

Ejemplares similares