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Pseudo-octahedral nickel(ii) complexes of strongly absorbing benzannulated pincer-type amido ligands: ligand-based redox and non-Aufbau electronic behaviour

The synthesis, structures and electronic characterization of three strongly coloured, pseudo-octahedral Ni(ii) complexes supported by redox-active diarylamido ligands featuring benzannulated N-heterocyclic donor arms are reported. The S = 1 paramagnets each present two singly occupied molecular orbi...

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Detalles Bibliográficos
Autores principales: Braun, Jason D., Lozada, Issiah B., Shepit, Michael, van Lierop, Johan, Herbert, David E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8694012/
https://www.ncbi.nlm.nih.gov/pubmed/35424319
http://dx.doi.org/10.1039/d0ra10761a