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Vibrational band-structures caused by internal rotations of the boron Wankel rotor B(11)(−)
Nuclear quantum effects are often neglected for systems without hydrogen atoms. However some planar boron rotors turn out to exhibit remarkable nuclear quantum effects. Recent experiment on infrared spectroscopy of B(13)(+) shows unexpected spectral broadening which still awaits physical explanation...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8694174/ https://www.ncbi.nlm.nih.gov/pubmed/35424268 http://dx.doi.org/10.1039/d0ra08821h |