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First cycloruthenation of 2-alkenylpyridines: synthesis, characterization and properties

Several cyclometalated ruthenium complexes 1–5 with 2-alkenylpyridines as C,N-chelating ligands were synthesized and then characterized by NMR, MS, IR and UV-Vis spectra. According to the single crystal of complex 2, it is evident that carbon from vinyl group is successfully bonded to Ru(ii) center....

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Detalles Bibliográficos
Autores principales: Wu, Yuhao, Su, Xianlong, Xie, Chaoyi, Hu, Rongrong, Li, Xianghong, Zhao, Qiang, Zheng, Guoli, Yan, Junkun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8694343/
https://www.ncbi.nlm.nih.gov/pubmed/35424326
http://dx.doi.org/10.1039/d0ra09833g