Cargando…
Cavity catalysis: modifying linear free-energy relationship under cooperative vibrational strong coupling
Here, we used an unconventional idea of cooperative vibrational strong coupling of solute and solvent molecules to enhance the rate of an esterification reaction. Different derivatives of p-nitrophenyl benzoate (solute) and isopropyl acetate (solvent) are cooperatively coupled to an infrared Fabry–P...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8694383/ https://www.ncbi.nlm.nih.gov/pubmed/35059167 http://dx.doi.org/10.1039/d1sc04707h |