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Light driven molecular lock comprises a Ru(bpy)(2)(hpip) complex and cucurbit[8]uril

Here, complex 1 ([Ru(bpy)(2)(hpip)](2+)–MV(2+)) and CB[8] can form a stable 1 : 1 inclusion complex in aqueous solution, resembling a U-shaped conformation. Upon light irradiation, two complex 1 were reversibly locked through the formation of a MV˙(+) radical dimer that is stabilized in the cavity o...

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Detalles Bibliográficos
Autores principales: Yang, Xiaona, Li, Jie, Jiang, Song, Xie, Puhui, Liu, Guoxing, Zheng, Xin, Cao, Zhanqi, Zheng, Xianfu, Zou, Dapeng, Wu, Yangjie, An, Wankai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695200/
https://www.ncbi.nlm.nih.gov/pubmed/35423371
http://dx.doi.org/10.1039/d0ra10940a