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Light driven molecular lock comprises a Ru(bpy)(2)(hpip) complex and cucurbit[8]uril
Here, complex 1 ([Ru(bpy)(2)(hpip)](2+)–MV(2+)) and CB[8] can form a stable 1 : 1 inclusion complex in aqueous solution, resembling a U-shaped conformation. Upon light irradiation, two complex 1 were reversibly locked through the formation of a MV˙(+) radical dimer that is stabilized in the cavity o...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695200/ https://www.ncbi.nlm.nih.gov/pubmed/35423371 http://dx.doi.org/10.1039/d0ra10940a |