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SrTi(IO(3))(6)·2H(2)O and SrSn(IO(3))(6): distinct arrangements of lone pair electrons leading to large birefringences
Three new iodates SrTi(IO(3))(6)·2H(2)O, (H(3)O)(2)Ti(IO(3))(6), and SrSn(IO(3))(6) have been synthesized via a facile hydrothermal method. The three compounds have zero-dimensional crystal structures composed of one [MO(6)](8−) (M = Ti, Sn) octahedron connected with six [IO(3)](−) trigonal pyramids...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8695646/ https://www.ncbi.nlm.nih.gov/pubmed/35423485 http://dx.doi.org/10.1039/d0ra10726c |